Masterarbeit, 2021
99 Seiten, Note: 4.5
Geowissenschaften / Geographie - Geologie, Mineralogie, Bodenkunde
1 INTRODUCTION
1.1 Orientation of the Proposed Study
1.1.1 World production of gold
1.1.2 Properties of gold
1.1.3 Uses of gold
1.2 Statement of Research Problem
1.3 Aim of Research
1.4 Objective of the Research
1.5 Justification
1.6 Scope of the Research
2 LITERATURE REVIEW
2.1 Geology of Gold Ore Deposits
2.1.1 Africa's gold deposits
2.1.2 Nigeria's gold deposits
2.2 Mineralogy of gold ore
2.2.1 Atomic absorption spectrometry (AAS)
2.2.2 X-ray fluorescence spectroscopy (XRF)
2.2.3 X-ray diffraction (XRD)
2.2.4 Electron microscopy
2.2.5 Scanning electron microscopy with energy-dispersive x-ray spectroscopy (SEM/EDS)
2.2.6 Transmission electron microscopy (TEM)
2.2.7 Scanning-transmission electron microscopy (STEM)
2.2.8 Ore microscopy
2.3 Mining
2.4 Mineral Processing
2.4.1 Comminution
2.4.2 Particle size analysis
2.5 Concentration Techniques
2.5.1 Gravity concentration
2.5.2 Froth flotation
2.6 Flotation Reagents
2.6.1 Collectors
2.6.2 Oxyhydrly collectors
2.6.3 Sulfhydrly collectors
2.6.4 Locally-Sourced Reagents
2.6.5 Convectional Reagents
2.7 Frothers
2.7.1 Groundnut oil
2.7.2 Methyl iso-butyl carbinol
2.8 Modifier
3 MATERIALS AND METHOD
3.1 Materials
3.2 Method
3.2.1 Sample collection and preparation
3.2.2 Chemical analysis of Iperindo lode gold ore sample
3.2.3 Mineralogical analysis of Iperindo lode gold ore
3.2.4 Preparation of collector
3.2.5 Froth flotation experiment for locally-sourced reagent
3.2.6 Froth flotation experiment for convectional reagent
4 RESULTS AND DISCUSSION
4.1 Chemical Analysis of Iperindo Lode Gold Ore
4.2 Mineralogical Analysis of Iperindo Lode Ore
4.4 The Effect of Pulp Density on the Recovery of Gold Concentrate
4.5 The Effect of Collector Concentration on the Recovery of Iperindo Lode Gold Concentrate
4.6 The Effect of Pulp pH on the Recovery of Iperindo Lode Gold Concentrate
4.7 The Effect of Impeller Speed on the Recovery of Iperindo Lode Gold Concentrate
4.8 The Optimum Recovery of Gold from Iperindo Lode Deposit at Vary Pulp Density Concentration of Collector, Pulp pH and Application of Impeller Speed
5 CONCLUSION AND RECOMMENDATIONS
5.1 Conclusion
5.2 Recommendation
5.3 Contribution to Knowledge
This thesis investigates the effectiveness of using locally-sourced reagents (groundnut oil derivatives) compared to conventional chemical reagents for the froth flotation of gold ore from the Iperindo lode. The primary goal is to determine if these local alternatives can improve processing efficiency, reduce costs, and provide an environmentally safer gold recovery method in Nigeria.
2.5.2 Froth flotation
Froth flotation is defined as a physico-chemical process which exploits the differences in the electrochemical properties of mineral surfaces, that is, between hydrophobic and hydrophilic surfaces, which either occur naturally or are artificially induced by chemical reagents (Yuan et al, 1996 and Bulatovic, 2010). In the flotation stage air bubbles generated in a flotation machine carry selected minerals to the top of the cell where they are collected for further processing. Particles having sufficient hydrophophibicity will be attached to the air bubbles while hydrophilic particles remain in the pulp (Yarar, 2000) and change of water quality can affect positively or negatively the flotation recovery (Liu et al., 2013). Hence, in any flotation pulp all three phases, solid, liquid and gaseous are present. The properties of the bulk phases influence determine the characteristics of the interfaces formed between the adjoining phases (Shean and Cillier, 2011). Applications of flotation method are widely used to separate different mineral particles ranging from sizes 10 to 100 μm. First, the ore is crushed and ground. Then the slurry is treated with flotation chemicals in a conditioning stage (Allan and Woodcock, 2001).
Many studies on the interactions between particles and bubbles, adsorption of reagents on minerals, novel flotation reagents, development of flotation machines and columns have been conducted with the aim of improving flotation efficiency and recovery. The rate of flotation is dependent of large number of variables that can be grouped in three major components according to Lourens (2015) are chemical, operational and equipment variables. However, the optimization and control of these variables is keys to the froth flotation process.
1 INTRODUCTION: Outlines the importance of the solid minerals industry to Nigeria's economy, the current state of gold mining, and the research problem regarding traditional, environmentally unfriendly extraction methods.
2 LITERATURE REVIEW: Examines the geological characteristics of gold deposits in Nigeria and Africa, and provides a theoretical overview of mineralogy, mining techniques, and froth flotation principles including collector and frother chemistry.
3 MATERIALS AND METHOD: Describes the materials sourced for the study and the specific experimental procedures, including sample preparation, chemical analysis, and the methodology for conducting froth flotation tests using both conventional and local reagents.
4 RESULTS AND DISCUSSION: Presents the findings of the chemical and mineralogical analysis and evaluates the impact of various flotation parameters (pulp density, pH, collector concentration, impeller speed) on gold recovery and grade.
5 CONCLUSION AND RECOMMENDATIONS: Summarizes the study's findings, confirming the viability of groundnut oil-based reagents as a sustainable alternative, and offers recommendations for future research.
Gold mining, Iperindo lode, Froth flotation, Locally-sourced reagents, Groundnut oil, Potassium amyl xanthate, Pulp density, Impeller speed, Mineral processing, Gold recovery, Sustainable mining, Chemical characterization, Mineralogical analysis, Gold concentrate, Hydrometallurgy
This work focuses on evaluating the amenability of Iperindo lode gold ore to froth flotation, specifically testing locally-sourced groundnut oil derivatives as a replacement for expensive, imported conventional flotation reagents.
The themes include the geological and mineralogical characterization of the Iperindo gold deposit, the theory of flotation reagent interaction, and the optimization of operational parameters to achieve sustainable gold recovery.
The primary aim is to establish the recovery efficiency of local reagents and compare their performance against conventional reagents like xanthates to promote more affordable and environmentally friendly mining in Nigeria.
The study utilized Atomic Absorption Spectrometry (AAS) and X-ray Fluorescence (XRF) for chemical analysis, X-ray Diffractometry (XRD) for mineralogical assemblage, and scanning electron microscopy (SEM/EDS) to analyze the ore's surface morphology.
The main body details the experimental setup for froth flotation, systematically varying parameters such as pulp pH, pulp density, collector concentration, and impeller speed to identify optimum conditions for maximum gold recovery.
Key terms include Gold mining, Froth flotation, Locally-sourced reagents, Iperindo lode, Sustainable mining, and Mineral processing optimization.
Groundnut oil is investigated because it is readily available, affordable, and contains fatty acids that can be chemically converted into effective collectors, offering a sustainable alternative to conventional organosulfur reagents.
The study found that the optimum pH for gold recovery using groundnut oil-based reagents is 9.0, whereas conventional xanthate-based reagents performed differently, achieving higher recovery at pH 10.
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