Bachelorarbeit, 2012
45 Seiten
1. Introduction
1.1 Background
1.2 Property of HDPE and LDPE
1.3 Sources and properties of plastic wastes
2. Literature review
2.1 Social and environmental impact of waste plastic
2.2 Plastic Waste management system
2.2.1 Recycling
2.2.2 Land filling
2.2.3 Incineration
2.2.4 Thermal cracking as a waste management option
2.3 Liquid Fuel Production
2.3.1 Thermal and catalytic recycling of waste plastic into crude oil
2.3.2 Thermal cracking
2.3.3 Catalytic cracking
2.4 Effect of major Operating Conditions
2.5 Statement of the problem
2.6 Objective
3. Methodology
3.1 Materials and chemicals needed
3.2 Experimental set up and description
3.3 Experiments
4. Result and discussion
4.1 Effect of temperature on the yield of crude oil from LDPE
4.2 Effect of temperature on crude oil from HDPE
4.3 Effect of temperature on crude oil from polystyrene
5. Product characterization
5.1 Determination of density
5.2 Determination of viscosity
5.3 Determination of flash point
6 Conclusion and Recommendation
The primary research objective of this thesis is to experimentally investigate the production of crude oil through the thermal cracking of various types of waste plastics. By analyzing the conversion process, the study aims to determine the impact of temperature and plastic types on oil yields and to characterize the physico-chemical properties of the produced oil compared to standard petroleum diesel.
1.1 Background
Plastic waste is regarded as a potentially cheap source of chemicals and energy. Lots of us have encountered a variety of products that use plastic materials today. As a result of the increasing level of private consumption of these plastic materials huge amount of wastes are discharged to the environment. Plastic materials are a type of material that cannot be decomposed easily in a short period of time. Substantial quantities of plastic have accumulated in the natural environment and in landfills. Those wastes can be classified as industrial and municipal according to their origins; these groups have different qualities and properties and are subjected to different management strategies [1]. Huge amounts of plastic wastes arise as a by-product or defective product in industry and agriculture. The main components of municipal solid waste (MSW) are food waste, wood, paper, cardboard, plastics, rubbers, fabrics, and metals. On the other words, more than half of the municipal solid waste components are organic species mainly thermoplastics, which can be used as energy sources. The traditional MSW disposal method is landfill. Because of the longevity of plastics, disposal to landfill may simply be storing problems for the future. For example, plasticizers and other additive chemicals have been shown to leach from landfills. The extent of this varies according to conditions, particularly pH and organic content. Recently, the conception of energy recovery from MSW has been a very hot topic. It is also undesirable to dispose of waste plastics by landfill due to poor biodegradability. An alternative strategy is that of chemical recycling, known as feedstock recycling or tertiary recycling, which has attracted much interest recently with the aim of converting waste plastics into basic petrochemicals to be used as chemical feedstock or fuels for a variety of downstream processes.
1. Introduction: Provides the context of plastic waste accumulation and outlines the potential for chemical recycling and energy recovery.
2. Literature review: Reviews existing waste management systems, thermal and catalytic cracking processes, and factors influencing fuel production.
3. Methodology: Details the experimental equipment, reactor construction, and the procedures used for processing and collecting oil samples.
4. Result and discussion: Presents the experimental data regarding temperature effects on oil yields for LDPE, HDPE, and polystyrene.
5. Product characterization: Explains the analytical methods used to measure density, viscosity, and flash point to validate the quality of the produced oil.
6 Conclusion and Recommendation: Summarizes the study findings regarding yields and suggests technical improvements for reactor design and heating methods.
waste plastic, waste management system, thermal cracking, characterization, low density polyethylene, high density polyethylene, polystyrene, pyrolysis, crude oil, fuel production, catalyst, reactor, feedstock recycling, density, viscosity
The thesis focuses on the experimental production of liquid crude oil from various waste plastics using thermal cracking (pyrolysis) as an environmentally friendly alternative to traditional landfill disposal.
The central themes include plastic waste management strategies, the chemical mechanism of thermal degradation, the impact of process variables like temperature on yield, and the characterization of the resulting fuel products.
The main objective is to assess the viability of converting waste plastic into usable fuel by investigating how different plastic types and cracking temperatures affect the quantity and quality of the produced oil.
The study uses an experimental batch reactor approach to thermally crack plastic samples at varying temperatures, followed by standard lab procedures to determine density, viscosity, and flash point.
The main body covers the theoretical background of plastic properties, detailed experimental setups, data analysis of oil production rates for different polymers, and the benchmarking of produced oil against commercial diesel standards.
Key terms include thermal cracking, pyrolysis, waste management, polyethylene (LDPE/HDPE), polystyrene, fuel characterization, and feedstock recycling.
These polymers, categorized as thermoplastics, are preferred because they contain suitable liquid hydrocarbon fractions that can be released and condensed during the thermal cracking process.
The study finds that the molecular structure, specifically the degree of branching and the prevalence of C-C versus C-H bonds, significantly influences the temperature at which cracking initiates and the final oil yield.
Temperature is identified as the critical operating variable; it dictates the rate of decomposition, the amount of gas versus liquid produced, and the formation of solid residues like coke.
The study concludes that converting waste plastic to fuel is feasible and recommends using better-sealed reactors and heat exchangers to minimize vapor loss and increase the efficiency of the condensation process.
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